Catalytic Upgrading of Pyrolysis Vapors from Scenedesmus sp. Microalgae towards Renewable Hydrocarbons using a Low-Cost Zeolite Synthesized from Rice Husk Ash and Diatomite Residue

Júlio de Andrade Oliveira Marques,José Luiz Francisco Alves, Karine Fonseca Soares de Oliveira,Dulce Maria de Araújo Melo, Graco Aurelio Camara de Melo Viana,Renata Martins Braga

BioEnergy Research(2024)

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摘要
The present study aims to investigate the potential for producing an aromatic hydrocarbon-enriched fuel from Scenedesmus sp. microalgae using low-cost zeolite in catalytic flash pyrolysis. The methodology adopted in this study involved the use of an analytical micropyrolyzer coupled with a gas chromatograph/mass spectrometer at 500 ºC to assess the effectiveness of the low-cost HZSM − 5 catalyst in deoxygenation, denitrogenation, and aromatization activities of volatile reaction products. The HZSM − 5 catalyst was synthesized using the hydrothermal method, employing low-cost precursor materials, rice husk ash, and diatomite residue as alternative silicon and aluminum sources. The oxygenated and nitrogenated volatile products in non-catalytic flash pyrolysis constituted 51.7
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关键词
Microalgae,Analytical pyrolysis,Acidic zeolite,Deoxygenation,Denitrogenation,Renewable hydrocarbons
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