Investigating New Environmentally Friendly Zeotropic Refrigerants as Possible Replacements for Carbon Dioxide (CO₂) in Car Air Conditioners

The widespread use of automobiles and the increased duration spent within automobiles equipped with air conditioning systems have prompted various countries to enforce regulations that advocate for eco-friendly cooling substances (refrigerants) characterized by a slight global warming potential (GWP) and the absence of an ozone depletion potential (ODP). The imperative for automobiles to possess air conditioning systems that are both high-performing and eco-conscious has emerged as a means to mitigate their ecological impact, reduce fuel usage, and minimize carbon emissions. Zeotropic refrigerants, with a lower GWP than traditional alternatives, contribute to sustainability in car air conditioning by reducing the environmental impact and enhancing the energy efficiency, aligning with global regulations and fostering innovation in the automotive industry. This shift signifies a commitment to mitigating climate change and adopting environmentally conscious practices. The objective of the present study is to introduce blends of zeotropic refrigerants based on CO2 (R-744), namely R455A (a blend of R-744, R-32, and R-1234yf), R469A (a blend of R-744, R-32, and R-125), and R472A (a blend of R-744, R-32, and R-134a), to enhance the thermodynamic performance of pure CO2 refrigerant. Through the utilization of the Aspen HYSYS V11 software, an investigation is carried out involving thermodynamic energy and exergy analyses, as well as system optimization for an automotive air conditioning (AAC) system utilizing these novel zeotropic refrigerant blends, in comparison with the use of R-744 as the refrigerant. The study delves into the impact of parameters such as average evaporator temperature, condenser/cooler pressure, refrigerant flow rate, and condenser/cooler outlet temperature on AACs' output parameters and subsequently presents the findings. The outcomes reveal that, under equivalent operational circumstances, the adoption of R455A, R469A, and R472A offers improvements in coefficient of performance (COP) by 35.4%, 18.75%, and 2%, respectively, when compared to R744. This shift is advantageous as it mitigates leakage-related issues stemming from the elevated operational pressure of R744 and eliminates the need for cumbersome equipment. R455A and R469A obtain the greatest COP and exergy efficiency (eta ex) values, measuring 4.44 and 4.55, respectively, at the identical operating conditions with optimal condenser/cooler pressures of the examined blends. Furthermore, eco-friendly refrigerants R455A and R472A are recommended for integration into AAC systems in vehicles, as they help combat global warming and protect natural surroundings and leakage issues.