Derivation and application of a parameter for denitrification rates in the Taihu Lake model based on an isotope-labeled denitrification experiment

Qiuxia Ma,Min Pang, Zhilin Huang, Ronghua Mu,Yong Pang

Environmental Science and Pollution Research(2024)

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摘要
In recent years, the total nitrogen concentration in Taihu Lake has decreased significantly. Denitrification, as the main nitrogen removal process, is the key reason for the decrease. Here, the denitrification parameter values in the Environmental Fluid Dynamic Code (EFDC) model were calculated based on isotope-labeled denitrification experiment instead of selecting the recommended values directly. This study further focused on EFDC denitrification parameter derivation with an experimental denitrification rate ( D tot ) to reduce simulation errors. According to the EFDC nitrate deposition flux mechanism, the conversion equation between the denitrification rate of the first sediment layer ( κ_1,NO_3 ) in EFDC and D tot was successfully derived. The results revealed a linear correlation between κ_1,NO_3 and ( D tot ) 1/2 . The κ_1,NO_3 values of sampling points ranged from 0.25 to 0.27 m·day −1 , within the range of model parameters. After substituting κ_1,NO_3 into the Taihu Lake EFDC model, the average percentage bias and determination coefficient of total nitrogen were 16.25
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关键词
EFDC,Denitrification,Equation derivation,Nitrogen isotope,Taihu Lake
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