Evaluating the Role of Functional Groups in the Selective Capture of Ag(I) onto UiO-66-Type Metal-Organic Frameworks

UiO-66-type metal-organic frameworks have been considered as promising adsorbents for capturing Ag(I) from wastewater. However, uncertainties persist regarding the specific absorptivity of individual functional groups to the UiO-66 framework structure. In this study, UiO-66-type metal-organic frameworks (UiO-66-X), featuring diverse functional groups (X = -(OH)(2), -(COOH)(2), -NO2, -NH2, -SO3H, -(SH)(2)), were synthesized in situ for Ag(I) capture. The findings revealed that functionalization significantly enhanced the adsorption capacity of Ag(I). Notably, quantitative analysis showed that 1 mol of -SH functional group onto the UiO-66 framework structure can adsorb 0.73 mol of Ag(I) ions, surpassing those of -COOH, -OH, -NH2, -SO3H, and -NO2 by 2.4-, 3.5-, 3.8-, 9.1-, and 24.3-fold, respectively. This represents the first assessment of the adsorption capacity of functionalized UiO-66 for Ag(I) based on each effective functional group, addressing limitations in traditional unit mass calculations. Further, the adsorption mechanism of UiO-66-X for selectively capturing Ag(I) was elucidated through experimental and theoretical analyses. Additionally, selectivity and practical applications confirm that UiO-66-(SH)(2) exhibits strong anti-interference ability, whether in natural water bodies with complex compositions or in industrial wastewater under harsh conditions. We anticipate that this study will enhance our understanding of structure-performance dependencies of multivariate MOFs for designing novel adsorbents for Ag(I) capture.