Plasmonic coupling-boosted photothermal composite photocatalyst for achieving near-infrared photocatalytic hydrogen production

The development of photocatalysts that effectively utilize low-energy photons for efficient photocatalysis still faces a number of challenges. Herein, an efficient NIR-driven system based on WO3-x/ZnIn2S4 (WO3-x/ZIS) prepared by a simple low-temperature water -bath method, and the optimal WO3-x/ZIS-3 composites can reach hydrogen -production efficiency of 14.05 mu mol g -1h- 1 under NIR light irradiation. The localized surface plasmon (LSPR) resonance effect in WO3-x quantum dots (QDs) not only broadens the ZIS photo-response range, but also the photothermal effect of WO3-x can increase the local reaction temperature of WO3-x/ZIS composite system, thus enhancing the photothermal-assisted photocatalytic activity. In addition, density functional theory (DFT) calculations show that the difference in work function between WO3-x and ZIS can lead to the formation of interfacial electric field (IEF), which not only promotes the separation and migration efficiency of photogenerated carriers, but also facilitates the photocatalytic water splitting for hydrogen production. This study provides possible directions for the construction of NIR-driven photothermal-assisted photocatalytic hydrogen production system.