Hydrothermal Mineralization and Mineral Chemistry of Arsenides and Sulfarsenides in the Fe-Co-Ni-As-S System and Introduction of Three Unique Minerals, Port Radium Deposit, Canada

The Port Radium U-Cu-Ni-Co-Ag deposit in northwestern Canada is hosted within a mineral system that has generated a variety of mineralization styles from iron oxide-copper-gold to iron oxide-apatite, porphyry, skarn, and epithermal. Their genesis is linked to an extensive subduction-related magmatism that formed widespread dacite-rhyodacite-andesite volcanic and volcanoclastic sequences (similar to 1.87 Ga), which have been intruded by their equivalent intrusive plutons. Pervasive and intensive hydrothermal alterations, including albitic, magnetite-actinolite-apatite, potassic +/- albitic, phyllic, and propylitic occurred before the main sulfide, sulfarsenide, and uraninite vein-type mineralization. Although scarce sulfide minerals formed at the beginning of the hydrothermal activity, the main polymetallic arsenide-sulfarsenide-sulfide +/- uraninite vein-type mineralization occurred during the epithermal stage. In addition to the common arsenides and sulfarsenides including nickeline, cobaltite, rammelsbergite, safflorite, skutterudite, gersdorffite, and arsenopyrite, three unique sulfarsenides were also found: Co0.67Ni0.32Fe0.02S0.19As2.80, which could be a sulfur-rich skutterudite, Ni0.85Co0.15S0.39As1.60, and Ni0.69Co0.31S0.47As1.52, which are chemically comparable to the Port Radium rammelsbergite with substantial addition of S and Co; they could be the solid solution product of gersdorffite-cobaltite or safflorite-rammelsbergite.