Bis(diphenyl)phosphinomethane Platinum(II) complex of 1-(benzo[d]thiazol-2-yl)-3-phenylthiourea: Crystal structure and DFT study

Alyaa S.M.O. Al-Barwari,Ahmed S. Faihan,Muhammad Ashfaq,Reza Behjatmanesh-Ardakani,Riyadh H. Al-Shammari,Muhammad Nawaz Tahir,Mohammad R. Hatshan,Ahmed S. Al-Janabi

Journal of Molecular Structure（2024）

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摘要

•1-(benzo[d]thiazol-2-yl)-3-phenylthiourea coordinates to Pt(II) in a square planar geometry in a mono-dentate, an ionic mode.•Mixed ligand complex of Bis(diphenyl)phosphinomethane Platinum(II) complex showed a dianion coordination mode.•A supramolecular assembly is stabilized by a couple of non-covalent or intermolecular interactions in the solid state

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关键词

1-(benzo[d]thiazol-2-yl)-3-phenylthiourea,Thiourea,supramolecular assembly,HOM-LUMO,DFT,dianion complex

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