Thiacalix[4]arene-protected mixed-valent Ti-CuICuII clusters for electrocatalytic CO2 reduction

Journal of Solid State Chemistry(2024)

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摘要
Two mixed-valent Ti-CuICuII clusters, Ti1Cu4 and Ti2Cu5, with different exposed CuI sites were synthesized by selecting 4-tert-Butylthiacalix[4]arene (H4TC4A) as an organic protective ligand. Electrocatalytic CO2 reduction reactions (CO2RR) studies indicate main HCOOH production for Ti1Cu4, and improved CH4 and CO production for Ti2Cu5.
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关键词
Ti-Cu clusters,thiacalix[4]arene,Electrocatalytic CO2 reduction
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