Syntheses, crystal structures, and energetic properties of four cyclo-pentazolate salts [NHn(CH3)4-n]+N5− (n = 0∼3)

Tianyang Hou,Yuangang Xu,Ze Xu,Xiaopeng Zhang,Ming Lu

Journal of Molecular Structure（2024）

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摘要

•Four cyclo-pentazolate salts [NHn(CH3)4-n]+N5− (n = 0∼3) were synthesized and fully characterized.•Hydrogen bond, cationic-π and π-π interactions affect the stability of the cyclo-N5−.•These salts all show low sensitivities (IS ≥ 35 J, FS > 360 N).

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关键词

Energetic material,Non-metallic pentazolate salt,Hydrogen bond,Weak interactions,Crystal structure

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