Lignin-derived nitrogen doped hierarchical porous carbon spheres for highly efficient dichloromethane adsorption

Biomass-prepared porous carbon materials are promising solid adsorbents for the removal of volatile organic compounds (VOCs). However, their application is hindered due to the insufficient number of pores and poor surface activity. In this study, a lignin-derived nitrogen-doped hierarchical porous carbon sphere (NHPCS-0.5) with abundant surface active sites was synthesised through spray drying and carbonisation-activation methods. The optimised NHPCS-0.5 displayed a high BET specific surface area (2961 m(2)center dot g(-1)) and total pore volume (1.57 cm(3)center dot g(-1)), developed hierarchical porous distribution with micro-/meso-/macropores and satisfactory surface nitrogen content. Moreover, it exhibited an excellent dichloromethane adsorption capacity of 156 mg center dot g(-1) and maintained 86% of initial capacity after five regeneration cycles, indicating an outstanding regenerative ability. The nitrogen introduction improved the micropore volume and adsorption capacity. Adsorption mechanism reveals that micropore filling and enhanced van der Waals interaction of carbon surface with dichloromethane molecule by N-containing functional groups played a vital role in adsorption, and mesopores contributed to the high adsorption rates. The above results indicate the potential of NHPCS-0.5 as an adsorbent for VOC removal and provide new ideas for the utilisation of lignin and design of carbon sphere materials.