Low-temperature magnetocaloric effect of the polyoxovanadate molecular magnet {VIV/V12As8}: An experimental study

Journal of Magnetism and Magnetic Materials(2024)

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摘要
•Experimental study of polyoxovanadate molecular magnet is reported.•Magnetic data analysis reveals a contribution from the off-center V4 units.•Isothermal magnetic entropy change is determined for high field-change values.•Rigorous estimation of the systematic errors in entropy change is performed.
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关键词
Polyoxometalates,Magnetocaloric effect,Magnetization,Susceptibility,Entropy
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