Conversion-intercalation competing behaviour of halogen storage on graphite electrode from fluid ZnCl₂/ZnBr₂ hydrates

Zinc-based aqueous dual-ion batteries (ADIBs) with halogen-graphite intercalation compound positive electrodes are among the most competitive candidates for next-generation electrochemical energy storage systems. However, most of the electrolytes employed have been gel-like electrolytes; hence, a fundamental understanding of the halogen storage process using fluid hydrates will be essential for constructing efficient Zn-based ADIBs. Herein, the halogen storage mechanism on a graphite electrode from fluid ZnCl2/ZnBr2 hydrates is studied by experimental and computational methods. The results indicate that the halogen storage mechanism is a competition between conversion and intercalation. Moreover, the macroscopic electrode reaction is determined by both the ion-pair solvation state at the graphite-electrolyte interface and the subsequent reactant supply is influenced by the electrode reaction rate.