Crystallization and luminescence properties of Er/Yb-doped glass-ceramics based on A2O-ZnO-SiO2 system (A = Li, Na, K, Cs)

Petr Vařák,Jan Baborák,Emmanuel Véron,Alena Michalcová, Jakub Volf,Mathieu Allix,Pavla Nekvindová

Journal of Non-Crystalline Solids（2024）

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摘要

•Crystallization in A2O-ZnO-SiO2 glass demonstrated (A = Li, Na, K, Cs).•Crystallization tendency decreases from Li20 to Cs2O.•Impact of crystallization on luminescence of Er3+ ions studied.•Luminescence intensity significantly enhanced in highly-crystalline samples.•Solubility of RE ions, such as Er3+or Yb3+, in zinc-based phases in highly limited.

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关键词

Erbium,Ytterbium,Luminescence,Silicate glass-ceramics,Zinc,Willemite

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