Impact of a CO2 leak on the release of major and trace elements according to groundwater flow conditions in a shallow freshwater carbonate aquifer: In-situ experiments and modelling

To investigate the role of hydrogeological conditions on the release of major and trace elements during CO2 leakage occurring in shallow freshwater aquifers in a CO2 Capture and Storage context, this paper compares the results of two in-situ CO2 leakage experiments. These experiments were carried out in a shallow freshwater carbonated aquifer located in Saint-Emilion, France, during both low and high-water levels periods. In both experiments, 200 L of carbonated water were injected into a well and groundwater monitoring was carried out downstream. Due to the physical heterogeneity of the aquifer at a small scale, the CO2-rich water plume did not follow the same flow path between the two hydrogeological periods, thus highlighting preferential pathways. It was observed that geochemical changes were not of the same intensity. The concentrations of Ca2+, HCO3 , Mg2+, Fe, Mn, As, Co, Cu, Ba, Sr and V increased during the low-water level experiment while the measured concentrations only reflected the dilution of the gasified water injected during the high-water level period.