Fabrication of a hierarchical NiTe@NiFe-LDH core-shell array for high-efficiency alkaline seawater oxidation

Xuexuan Ju,Xun He, Yuntong Sun,Zhengwei Cai, Shengjun Sun,Yongchao Yao, Zixiao Li,Jun Li, Yan Wang,Yuchun Ren, Binwu Ying, Yongsong Luo,Dongdong Zheng, Qian Liu,Lisi Xie, Tingshuai Li, Xupin Sun,Bo Tang

ISCIENCE(2024)

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摘要
Herein, a hierarchical NiTe@NiFe-LDH core-shell array on Ni foam (NiTe@NiFe-LDH/NF) demonstrates its effectiveness for oxygen evolution reaction (OER) in alkaline seawater electrolyte. This NiTe@NiFe-LDH/ NF array showcases remarkably low overpotentials of 277 mV and 359 mV for achieving current densities of 100 and 500 mA cm -2, respectively. Also, it shows a low Tafel slope of 68.66 mV dec-1. Notably, the electrocatalyst maintains robust stability over continuous electrolysis for at least 50 h at 100 mA cm -2. The remarkable performance and hierarchical structure advantages of NiTe@NiFe-LDH/NF offer innovative insights for designing efficient seawater oxidation electrocatalysts.
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