High-performance supercapacitor based on NiCo2S4/g-C3N4/polyaniline deposited on carbon cloth for structural stability

SYNTHETIC METALS(2024)

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摘要
Although the synthesis of NiCo2S4(NCS)/g-C3N4(GCN)/PANI as an electroactive material has been extensively documented, assembling a Nickel cobalt sulfide (NCS) electrode with outstanding electrochemical efficiency at high current density is still difficult. In this work, the fabrication of a supercapacitor (Sc) electrode of petal -like NiCo2S4/g-C3N4/PANI using a hydrothermal, thermal condensation, and chemical oxidative polymerization method was done. In this nanocomposite, g-C3N4 stabilized the metal atoms and PANI integration considerably improves ion mobility, leading to rapid charge transmission. Due to improvement in electron mobility, the eventual NiCo2S4/g-C3N4(0.40wt%) /PANI(A-3) electrode had shown a specific capacitance (Cs) of 3.4 F/cm2 (1799.07 F/g) with 90% retention and 2700 cycles at the current density of 2 mA/cm2. A good rate capacity of 87.36% at 5 mA/cm2, 82.92% at 10 mA/cm2, and a 50.35% decline of its original capacitance at a high charge/ discharge current density of 20 mA/cm2. This work demonstrates that the produced NiCo2S4/g-C3N4/PANI electrode has a high potential for use in energy storage gadget technologies.
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关键词
Energy storage,PANI,Petal-like structure,Structural stability,Polyaniline
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