Spectral and temporal properties of 5-phenyl-2-[4-(5-phenyl-1,3-oxa-zol-2-yl)phenyl]-1,3-oxazole (POPOP) multiphoton-excited luminescence

The results of a study of multiphoton-excited luminescence and Stimulated Raman scattering (SRS) of POPOP in a form of crystalline powder and toluene solution are presented. Two-photon and three-photon-excited luminescence in POPOP crystalline powder and toluene solution was registered under excitation by pico- and nanosecond laser pulses. Samples cooling to the temperature of liquid nitrogen leads to the appearance of an additional line in the luminescence spectrum at a wavelength of 447 nm, SRS lines intensity increasing accompanying two-photon luminescence process and changing temporal dynamics, a decrease in the contribution of the fast component in the decay time curve.