In‐situ study of degradation in PTB7:PCBM films prepared with the binary solvent additive DPE:DIO

Abstract Blend films of poly[[4,8‐bis[(2‐ethylhexyl)oxy]benzo[1,2‐b:4,5‐b']dithiophene‐2,6‐diyl][3‐fluoro‐2‐[(2‐ethylhexyl)carbonyl]thieno[3,4‐b]thiophenediyl]] (PTB7) in combination with 6,6‐phenyl‐C61‐butyric‐acid‐methyl‐ester (PCBM) are a model system for low bandgap organic photovoltaics. Typically, solvent additives are used to improve the power conversion efficiencies of the resulting devices but possibly also decrease the device stability. In this study, we use the binary solvent additive 1,8‐diiodooctane:diphenylether (DIO:DPE) for PTB7:PCBM blend films and study how different film drying procedures influence the physical and chemical stability of the polymer blend. The strong influence of the drying procedure on the stability against photoinduced degradation of the PTB7:PCBM films, produced with solvent additives, is shown with data from UV–visible (UV–vis), Fourier transform infrared (FTIR) and Raman spectroscopy. The addition of solvent additive molecules DIO:DPE to the PTB7:PCBM blend accelerates the degradation compared with the pristine blend. At higher annealing temperature a removal of the additives is bringing degradation back to the level of the pristine blend films, which is promising for photovoltaic applications.