Metal-free, visible-light driven α-C(sp3)−H gem-difluoroallylation of glycine derivatives with trifluoromethyl alkenes and 1,3-enynes

Li Guo,Zi-Hang Yuan,Xin Hong,Lu Zhang,Pin Gao, Yang Xu,Xin‐Hua Duan

Green Chemistry（2023）

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摘要

A metal free, visible-light driven α-C(sp 3 )−H gem-difluoroallylation of glycine derivatives with CF 3 -alkenes and 1,3-enynes is presented under redox-neutral conditions with good yields and excellent functional group compatibility.

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关键词

trifluoromethyl alkenes,glycine derivatives,metal-free,visible-light,gem-difluoroallylation

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