Elucidating the Intimate Mechanism of NAD+ hydrogenation with Phosphonic Acid Catalysed by Cp*Ir(Pyridine-2-sulfonamidate) Complexes

Leonardo Tensi,Luca Rocchigiani,Gabriel Menendez Rodriguez,Edoardo Mosconi,Cristiano Zuccaccia,Filippo De Angelis,Alceo Macchioni

Catalysis Science & Technology（2023）

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摘要

Cp*Ir(pyridine-2-sulfonamidate) complexes undergo pyridine displacement when catalysing nicotine amide dinucleotide hydrogenation in the presence of phosphonic acid, thus explaining the molecular origin of their improved performance.

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关键词

phosphonic acid catalysed

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