Ruthenium complexes of 1,4-diazabutadiene ligands with a cis-RuCl₂ moiety for catalytic acceptorless dehydrogenation of alcohols: DFT evidence of chemically non-innocent ligand participation

A. K. Mukherjee,Sayanti Datta,Michael G. Richmond,Samaresh Bhattacharya

RSC Advances（2023）

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摘要

A family of diazabutadiene bound ruthenium compounds bearing a RuCl 2 moiety has been synthesized, and catalytic efficiency of their cis -isomer for the coupling of primary alcohols to esters has been studied.

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ligands,catalytic acceptorless dehydrogenation,ruthenium,complexes,non-innocent

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Ruthenium complexes of 1,4-diazabutadiene ligands with a cis-RuCl2 moiety for catalytic acceptorless dehydrogenation of alcohols: DFT evidence of chemically non-innocent ligand participation

Ruthenium complexes of 1,4-diazabutadiene ligands with a cis-RuCl₂ moiety for catalytic acceptorless dehydrogenation of alcohols: DFT evidence of chemically non-innocent ligand participation