Diastereodivergent cis- and trans-fused [4 + 2] annulations of cyclic 1,3-dienes and 1-azadienes via ligand-controlled palladium catalysis

Y. Hu,Jinyu Huang,Ru‐Jie Yan, Zhichao Chen,Qin Ouyang,Wei Du,Ying‐Chun Chen

Chemical Science（2023）

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摘要

Diastereodivergent and asymmetric [4 + 2] annulations between cyclic 1,3-dienes and 1-azadienes via ligand-controlled Pd catalysis have been realized, furnishing both cis - and trans -fused tetrahydropyridines in good yields and stereoselectivity levels.

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关键词

diastereodivergent,catalysis,<i>cis</i>-,ligand-controlled

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