Exploiting reduced-symmetry ligands with pyridyl and imidazole donors to construct a second-generation stimuli-responsive heterobimetallic [PdPtL₄]⁴⁺ cage

Aston C Pearcy,Lynn S. Lisboa,Dan Preston, Natalie Page,Tristan Lawrence,L. James Wright,Christian G. Hartinger,James D. Crowley

Chemical Science（2023）

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摘要

A new method for the assembly of a heterobimetallic [PdPtL 4 ] 4+ cage which can interact with anionic guest molecules in a specific, selective host–guest orientation is described.

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关键词

ligands,pyridyl,pdptl<sub>4</sub><sup>4+</sup>,reduced-symmetry,second-generation,stimuli-responsive

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Exploiting reduced-symmetry ligands with pyridyl and imidazole donors to construct a second-generation stimuli-responsive heterobimetallic [PdPtL4]4+ cage

Exploiting reduced-symmetry ligands with pyridyl and imidazole donors to construct a second-generation stimuli-responsive heterobimetallic [PdPtL₄]⁴⁺ cage