Triplet Conformation in Chromophore-fused Cyclooctatetraene Dyes

Sunandita Paul,Hidetsugu Kitakado, Kyôichi Suga,Ryota Kotani,Nilanjan Dey,Eduard Matito,Ravindra Venkatramani,Shohei Saito,Jyotishman Dasgupta

Journal of Materials Chemistry C（2023）

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摘要

Cyclooctatetraene (COT) is predicted to have a planar aromatic triplet state. Using femtosecond-to-microsecond transient absorption spectroscopy, we show that acene chromophore-fused COT dyes also have a planar COT ring in their triplet states, although they are not aromatic.

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关键词

conformation,chromophore-fused

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