Electrochemical Chemoselective Hydroxyl Group Transformation: Anthranilic Acyl modification of Tyrosine Bioconjugations

Shiqi You, Ruitao Wang,Chao Ma,Cuifen Lu,Guichun Yang,Liu Li,Yue Weng,Meng Gao

Organic chemistry frontiers（2023）

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摘要

We report an electrochemically promoted transformation for accessing tyrosine-containing biomolecules with anthranilic acid derivatives. Utilizing TBAF as the hydrogen-bonding additive, the tyrosine residue can be well labelled under mild conditions.

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anthranilic acyl modification

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