Structural features that modulate the sharpness of the spin crossover transition in [Fe^III(5-X-qsal)₂]⁺ based salts

Bruno Vieira,Laura C. J. Pereira, V. Gama,J.C. Waerenborgh

CrystEngComm（2023）

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摘要

In a series of compounds based on [Fe(5-X-qsal) 2 ] + the reinforcement of the interchain connectivity and the weakening of the interlayer interactions increase the sharpness of the spin crossover transition.

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spin crossover transition,salts,features,x-qsal

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Structural features that modulate the sharpness of the spin crossover transition in [FeIII(5-X-qsal)2]+ based salts

Structural features that modulate the sharpness of the spin crossover transition in [Fe^III(5-X-qsal)₂]⁺ based salts