Bulky magnesium(ii) and sodium(i) bisphenoxide catalysts for chemoselective transesterification of methyl (meth)acrylates

Xue Zhao,Manussada Ratanasak,Kazumasa Kon,Jun‐ya Hasegawa,Kazuaki Ishihara

Chemical Science（2023）

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摘要

Bulky Mg( ii ) and Na( i ) bisphenoxides have been developed as extremely effective catalysts for the chemoselective transesterification of methyl (meth)acrylates. Plausible mechanisms are proposed based on the results of XRD and DFT calculations.

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关键词

chemoselective transesterification,bisphenoxide catalysts

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