MnBr(CO)₅: a commercially available highly active catalyst for olefin hydrosilylation under ambient air and green conditions

Anthony Vivien,Laurent Veyre,Raphaël Mirgalet,Clément Camp,Chloé Thieuleux

Green Chemistry（2023）

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摘要

Commercially available MnBr(CO) 5 was found to be a remarkable catalyst for olefin hydrosilylation reactions using a wide range of olefins and silanes. This system tolerates unpurified substrates and can be used in green solvents under ambient air.

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olefin hydrosilylation,active catalyst

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MnBr(CO)5: a commercially available highly active catalyst for olefin hydrosilylation under ambient air and green conditions

MnBr(CO)₅: a commercially available highly active catalyst for olefin hydrosilylation under ambient air and green conditions