Hf⁴⁺-exchanged montmorillonite-boosted Pd-catalyzed reductive aminolysis of aryl ethers to efficiently synthesize cyclohexylamines

Jizheng Xu,Bingxiao Zheng,Jinliang Song,Haihong Wu,Xuelei Mei,Kaili Zhang,Wanying Han, Li Chunyu, Min He,Buxing Han

Green Chemistry（2023）

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摘要

A robust and completely heterogeneous catalyst, Pd/Hf-MMT, was highly efficient for reductive aminolysis of aryl ethers to producce N -cyclohexyl-substituted amines at a low H 2 pressure of 0.3 MPa without using any homogeneous acidic additives.

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cyclohexylamines,aryl ethers,montmorillonite-boosted,pd-catalyzed

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Hf4+-exchanged montmorillonite-boosted Pd-catalyzed reductive aminolysis of aryl ethers to efficiently synthesize cyclohexylamines

Hf⁴⁺-exchanged montmorillonite-boosted Pd-catalyzed reductive aminolysis of aryl ethers to efficiently synthesize cyclohexylamines