A highly conducting mixed-valence nickel bis(dithiolene) salt [Et₄N][Ni(Me-thiazSe-dt)₂]₂ with selone substitution

Hadi Hachem,Olivier Jeannin,Hongchang Cui,Reìzo Kato,Marc Fourmigué,Dominique Lorcy

Dalton Transactions（2023）

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摘要

High conductivity is found in a 1 : 2 mixed-valence salt of a selone-substituted nickel bis(dithiolene) complex with a rare cis arrangement of the two dithiolene ligands around the Ni atom.

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nickel,nickel,bisdithiolene,mixed-valence,me-thiazse-dt

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A highly conducting mixed-valence nickel bis(dithiolene) salt [Et4N][Ni(Me-thiazSe-dt)2]2 with selone substitution

A highly conducting mixed-valence nickel bis(dithiolene) salt [Et₄N][Ni(Me-thiazSe-dt)₂]₂ with selone substitution