Understanding the structural landscape of Mn-based MOFs formed with hinged pyrazole carboxylate linkers

Josephine Frances Smernik,Pol Gimeno-Fonquernie,Jorge Albalad, Tom R. Jones,Rosemary J. Young,Neil R. Champness,Christian J. Doonan,Jack D. Evans,Christopher J. Sumby

CrystEngComm（2023）

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摘要

Isoreticulation of MOFs made of pyrazole carboxylate linkers and Mn nodes is nontrivial due to linker flexibility and a variety of accessible Mn nodes. The use of tetratopic hinged linkers to form porous 3D MOFs was identified as a viable strategy.

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关键词

hinged pyrazole carboxylate linkers,mofs,structural,mn-based

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