[Au(Np#)Cl]: Highly Reactive and Broadly Applicable Au(I)–NHC Catalysts for Alkyne pi-Activation Reactions

Md. Mahbubur Rahman,Pengcheng Gao,Qun Zhao,Roger A. Lalancette,Roman Szostak,Michal Szostak

Catalysis Science & Technology（2023）

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摘要

We report [Au(NHC)Cl] complexes featuring IPr# ligands that hinge upon modular peralkylation of aniline. Wingtip-flexible [Au(Np#)Cl] is a broadly applicable catalyst with the reactivity outperforming [Au(IPr)Cl] and [Au(IPr*)Cl] complexes.

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关键词

catalysts,aunp#cl,pi-activation

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