Synthesis and Functionalization of the Six-Vertex Anionic Amido-Substituted Silicon Cluster [Si6{N(SiMe3)Ph}5]−

Felicitas Lips,Joschua Helmer,Alexander Hepp,Raphael J. F. Berger

Dalton Transactions（2023）

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摘要

Reaction of the amido-substituted silicon cluster Si 6 {N(SiMe 3 )Ph} 6 1 with two equiv. of KC 8 results in the anionic silicon cluster [Si 6 {N(SiMe 3 )Ph} 5 ] — 2 that reacts with MeI, SiCl 4 and SiBr 4 to neutral double functionalized silicon clusters.

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关键词

silicon,six-vertex,amido-substituted

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