A novel chelating bidentate NHC ligand based on the cationic (η5-cyclopentadienyl)(η6-arene)iron(II) motif

Christian Malchau,Nicole Ultes,Julia Ehrhard,Tobias R. Eger,Daniela V. Fries,Benjamin Oelkers,Sabine Becker,Gereon Niedner‐Schatteburg,Werner R. Thiel

Journal of Organometallic Chemistry（2023）

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摘要

We here present the synthesis of a novel chelating N-heterocyclic carbene (NHC) ligand with the two NHC moieties bound to a cationic (η5-cyclopentadienyl)(η6-arene)iron(II) center and its coordination to palladium(II). Spectroscopic and spectrometric characterization, together with X-ray structural analyses, proves the molecular structure of these new organometallic compounds.

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关键词

bidentate nhc ligand,η5-cyclopentadienylη6-areneironii

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