Electrochemical N-Acylation and N-α-Ketoacylation of Sulfoximines via the Selective Decarboxylation and Dehydration of α-Ketoacids

Fanghua Ji,Kang Chen, Mingzhe Li, Wenxiu Huang,Shoucai Wang, Peng Mei, Lili Zhao,Guangbin Jiang

Green Chemistry（2023）

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摘要

We describe an electrochemical N -acylation and N -α-ketoacylation of sulfoximines via the selective decarboxylation and dehydration of α-ketoacids using electricity as a “traceless” oxidant and α-ketoacid as a selective “acyl” or “α-ketoacyl” source.

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关键词

sulfoximines,selective decarboxylation,n-acylation

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