Bond breaking of furan–maleimide adducts via a diradical sequential mechanism under an external mechanical force

Manuel Cardosa-Gutierrez,Guillaume De Bo,Anne‐Sophie Duwez,Françoise Remacle

Chemical Science（2023）

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摘要

An external mechanical force larger than 1 nN induces a switch from a concerted to a stepwise mechanism in the rupture of proximal dimethyl furan–maleimide [4 + 2] Diels–Alder adducts. The intermediate formed after the first bond rupture has a diradical character.

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关键词

furan–maleimide adducts,bond breaking,diradical sequential mechanism,external mechanical force

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