Cubane-type Tungsten-Iron-Sulfur Clusters with Nitrogen Atom in the Core: Terminal Ligand Substitutions and Redox Behaviors

Hongying Zhang,Shu-Juan Qiu,Huanhuan Yang,Mengting Wang,Jie Yang,Hanbin Wang,Nai-Hao Liu,Xudong Chen

Dalton Transactions（2023）

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摘要

Terminal ligand replacement in combination with core redox chemistry has been carried out based on a cluster comprising a [WFe 3 S 3 N] cubane core, raising the possibility of regulating the electrochemical properties of M–Fe–S clusters with core 2p atom(s).

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关键词

nitrogen atom,terminal ligand substitutions,cubane-type,tungsten-iron-sulfur

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