Transition-metal-free chemoselective catalytic hydrosilylation of tertiary amides to hemiaminals by Me₂SiH₂ generated from controllable disproportionation of 1,1,3,3-tetramethyldisiloxane

Xiaoyu Wu,Yue Wang,Liqun Yang,Xiaomin Xie,Zhaoguo Zhang

Organic chemistry frontiers（2023）

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摘要

We present a KO t Bu-catalyzed hydrosilylation for the chemoselective reduction of various tertiary amides to hemiaminals. Mechanistic investigations reveal a controllable disproportionation of TMDS to generate the distinctive reductant Me 2 SiH 2 .

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关键词

tertiary amides,hemiaminals,transition-metal-free

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Transition-metal-free chemoselective catalytic hydrosilylation of tertiary amides to hemiaminals by Me2SiH2 generated from controllable disproportionation of 1,1,3,3-tetramethyldisiloxane

Transition-metal-free chemoselective catalytic hydrosilylation of tertiary amides to hemiaminals by Me₂SiH₂ generated from controllable disproportionation of 1,1,3,3-tetramethyldisiloxane