Highly Diastereo- and Enantioselective Synthesis of Spiro β-Lactams via Copper-Catalyzed Kinugasa/Aldol Cascade Reaction

Jie Liu,Haowen Ma, Xingfu Zhong, S. Li,Jiehao Zhang,Yun-Lin Ao,Wei Zhou,Qian Cai

Organic chemistry frontiers（2023）

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摘要

A copper( i )-catalyzed highly diastereo- and enantioselective Kinugasa/aldol cascade reaction of N -(2-acylaryl) propiolamides with nitrones has been demonstrated for efficient synthesis of structurally novel chiral spiro β-lactams.

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enantioselective synthesis,copper-catalyzed

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