Thermal N–O bond heterolysis of TEMPO-CF₂CF₃ towards trifluoroacetylation of alcohols and amines

Organic chemistry frontiers（2023）

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摘要

A perfluoroalkoxyamine TEMPO-CF 2 CF 3 can be synthesized on gram-scale and it undergoes unusual N–O bond heterolytic cleavage under thermal conditions.

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trifluoroacetylation

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Thermal N–O bond heterolysis of TEMPO-CF2CF3 towards trifluoroacetylation of alcohols and amines

Thermal N–O bond heterolysis of TEMPO-CF₂CF₃ towards trifluoroacetylation of alcohols and amines