Ti₃C₂‐modified g‐C₃N₄/MoSe₂ S‐Scheme Heterojunction with Full‐Spectrum Response for CO₂ Photoreduction to CO and CH₄

Energy shortage and global warming caused by the extensive use of fossil fuels are urgent problems to be solved at present. Photoreduction of CO2 is considered to be a feasible solution. The ternary composite catalyst g-C3 N4 /Ti3 C2 /MoSe2 was synthesized by hydrothermal method, and its physical and chemical properties were studied by an array of characterization and tests. In addition, the photocatalytic performance of this series of catalysts under full spectrum irradiation was also tested. It is found that the CTM-5 sample has the best photocatalytic activity, and the yields of CO and CH4 are 29.87 and 17.94 μmol g-1 h-1 , respectively. This can be ascribed to the favorable optical absorption performance of the composite catalyst in the full spectrum and the establishment of S-scheme charge transfer channel. The formation of heterojunctions can effectively promote charge transfer. The addition of Ti3 C2 materials provides plentiful active sites for CO2 reaction, and its superior electrical conductivity is also favorable for the migration of photogenerated electrons.