Understanding the role of Zn vacancy induced by sulfhydryl coordination for photocatalytic CO₂ reduction on ZnIn₂S₄

Yu Nie,Tingting Bo,Wei Zhou,Huilin Hu,Xiang Huang,Huaiyuan Wang,Xin Tan,Lequan Liu,Jinhua Ye,Tao Yu

Journal of materials chemistry. A, Materials for energy and sustainability（2023）

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摘要

Zn vacancy ZnIn 2 S 4 tuned Gibbs free energy of *COOH which is the rate determining step of phototcatalytic CO 2 reduction from endothermic to exothermic process.

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photocatalytic coordination,sulfhydryl coordination,zn vacancy,znin<sub>2</sub>s<sub>4</sub>

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Understanding the role of Zn vacancy induced by sulfhydryl coordination for photocatalytic CO2 reduction on ZnIn2S4

Understanding the role of Zn vacancy induced by sulfhydryl coordination for photocatalytic CO₂ reduction on ZnIn₂S₄