Voltammetric Detection of Explosive Nitroaromatic Compounds Using Boron-Doped Carbon Nanowall Electrodes

Nitroaromatic highly energetic explosive compounds were widely used during the I and II World Wars. Some of them, like 2,4,6-trinitrotoluene (TNT), are still used in military munitions or in industrial applications i.e., underwater blasting, mining, deep well or dye production. The worldwide use of nitroaromatic compounds led to widespread pollution of the environment causing a danger to living organisms due to their high toxicity and possible carcinogenicity. The most commonly used techniques for the detection of explosive nitroaromatics are high-performance liquid chromatography or high-resolution gas chromatography coupled with different detectors like mass spectrometers. Both methods require: expensive instrumentation, complex sample preparation which is crucial to analysis, and well-trained staff to perform the experiments. Therefore it is difficult to implement chromatography in the field. Electrochemical sensing is emerging as a fast, sensitive and relatively simple technique for detecting explosive materials. To date, various materials have been used as working electrodes for this purpose, however, carbon materials are particularly promising [1-2]. Among carbonaceous materials, boron-doped carbon nanowall (B:CNW) electrodes are particularly attractive for the sensitive and rapid detection of nitro-based compounds [3] due to the high content of sp 2 phase, wide electrochemical working potential window (from -1.6 V to 1.2 V in 0.5 M KCl) and high values of heterogeneous electron transfer rate constant. In this work, we present electrochemical detection of chosen nitroaromatic explosive compounds like TNT on boron-doped carbon nanowall electrodes in aqueous solutions using voltammetric electrochemical techniques (differential pulse voltammetry, square-wave voltammetry, cyclic voltammetry). B:CNW electrodes were obtained using microwave plasma-assisted chemical vapour deposition in a one-step growth process. B:CNW electrode show enhanced electrocatalytic activity towards nitro moieties attached to aromatic rings, resulting in improved sensitivity toward detecting these groups. Hence, it is an attractive nanocarbon surface for nitroaromatic compound determination. References [1] M. Goh et al., Anal Bioanal Chem 2011, 399, 127–131. Doi: 10.1007/s00216-010-4338-8 [2] A. Dettlaff et. al, Microchimica Acta, 2022, 189:270. Doi: 10.1007/s00604-022-05371-w [3] A. Dettlaff et al., J. Hazard. Mater. 2020, 387, 121672. Doi: 10.1016/j.jhazmat.2019.121672 Acknowledgements The research leading to these results has received funding from the Norway Grants 2014-2021 via the National Centre for Research and Development within research grant no. NOR/SGS/NITROsens/0011/2020-00