Pathway to Construct -Acyloxy Esters by B(C₆F₅)₃-Catalyzed O-H Insertion of Carboxylic Acids with Sulfoxonium Ylides

Shuran Xu,Qingyao Zhang,Yuanyuan Li,Cankun Luo,Ruizhi Lai,Li Guo,Li Hai,Guanghui Lv,Yong Wu

JOURNAL OF ORGANIC CHEMISTRY（2023）

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摘要

We report the first example of B-(C6F5)(3)-catalyzed O-H insertion reaction of sulfoxonium ylides and carboxylic acids, achieving efficient construction of diester moieties under metal-free condition. This protocol is characterized by broad substrate tolerance, particularly for various phenylacetic acids, and good compatibility with water/air condition, which is superior to most other methods.

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carboxylic acids,esters

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Pathway to Construct -Acyloxy Esters by B(C6F5)3-Catalyzed O-H Insertion of Carboxylic Acids with Sulfoxonium Ylides

Pathway to Construct -Acyloxy Esters by B(C₆F₅)₃-Catalyzed O-H Insertion of Carboxylic Acids with Sulfoxonium Ylides