Cycloaddition of N-arylnitrones with donor–acceptor oxiranes via C–C bond cleavage to construct 1,5,2-dioxazinanes

Wenhui Li,Jianying Lin,Shuangping Huang,Qiang Liu,Wenlong Wei,Xing Li

Organic & Biomolecular Chemistry（2023）

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摘要

Multisubstituted 1,5,2-dioxazinanes could be smoothly produced by adopting a Sc(OTf)3-catalyzed [3 + 3] cycloaddition of N-arylnitrones with donor–acceptor oxiranes via C–C bond cleavage.

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关键词

donor–acceptor oxiranes,cycloaddition

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