Comparative Theoretical Study of N-Heterocyclic Carbenes and Other Ligands Bound to AuI
Chemistry-An Asian Journal（2006）
摘要
Abstract The bonding strength of N‐heterocyclic carbene (NHC) ligands to a neutral AuCl test moiety are compared to that of several phosphanes and other ligands. Of the ligands studied, the NHCs clearly form the strongest bonds to AuCl. A simplified triangular CN 2 model is also introduced for the NHCs.
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关键词
other ligands,aui,n-heterocyclic
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