Synthesis of highly polarized [3]dendralenes and their Diels–Alder reactions

Rastislav Antal,Monika Staś,Stefanie M. Perdomo,Marie Štemberová,Zbyněk Brůža,Petr Matouš,Jiří Kratochvíl,Aleš Růžička,Lubomı́r Rulı́šek,Jiřı́ Kuneš,Pavel Kočovský,Erik Andris,Milan Pour

Organic chemistry frontiers（2023）

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摘要

Strongly electron-deficient dendralenes prepared in 3 steps from methyl propiolate undergo smooth diene-transmissive Diels–Alder reactions with strongly electron-deficient dienophiles.

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关键词

polarized,diels–alder reactions,synthesis

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