Iron catalyzed β-C(sp²)–H alkylation of enamides

Sylvain Bertho,Radhouan Maazaoui,Damla Torun,Ismaël Dondasse,Raoudha Abderrahim,Cyril Nicolas,Isabelle Gillaizeau

New Journal of Chemistry（2021）

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摘要

An attractive and cheap alternative approach was developed for the β-C(sp 2 )–H (fluoro)alkylation of a range of cyclic and acyclic non-aromatic enamides using either FeCl 2 as a catalyst or a stoichiometric amount of nontoxic iron powder.

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enamides,iron

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Iron catalyzed β-C(sp2)–H alkylation of enamides

Iron catalyzed β-C(sp²)–H alkylation of enamides