Cobalt(iii)–salen decorated stereoregular optically active helical polyisocyanides enable highly effective cooperative asymmetric catalysis toward the kinetic resolution of epoxides

Shu‐Ming Kang, She–Sheng Xue,Tingting Zhang,Lei Xu,Yunlong Zhu,Zong‐Quan Wu

Inorganic chemistry frontiers（2023）

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摘要

The decoration of Co( iii )–salen onto stereoregular optically active helical polyisocyanides considerably increased efficiency and enantioselectivity of kinetic resolution of epoxides through improved cooperative asymmetric catalysis mode.

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关键词

active helical polyisocyanides,effective cooperative asymmetric catalysis

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