A halogenophilic pathway in the reactions of transition metal carbonyl anions with [(η⁶-iodobenzene)Cr(CO)₃]

Petr K. Sazonov,Vasiliy A. Ivushkin,Victor N. Khrustalev,Natal'ya G. Kolotyrkina,Irina P. Beletskaya

Dalton Trans.（2014）

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摘要

Formal nucleophilic substitution in [(η6-iodobenzene)Cr(CO)3] begins with the attack of the carbonylmetallate at iodine to form the aryl carbanion and [IM(CO)nL], which then give all of the variety of products observed.

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关键词

transition metal carbonyl anions,halogenophilic pathway,reactions

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A halogenophilic pathway in the reactions of transition metal carbonyl anions with [(η6-iodobenzene)Cr(CO)3]

A halogenophilic pathway in the reactions of transition metal carbonyl anions with [(η⁶-iodobenzene)Cr(CO)₃]